Solar cell - pin mặt trời

Solar cell - pin mặt trời

Converting Photons to Electrons
The solar cells that you see on calculators and satellites are photovoltaic cells or modules (modules are simply a group of cells electrically connected and packaged in one frame). Photovoltaics, as the word implies (photo = light, voltaic = electricity), convert sunlight directly into electricity. Once used almost exclusively in space, photovoltaics are used more and more in less exotic ways. They could even power your house. How do these devices work?
Photovoltaic (PV) cells are made of special materials called semiconductors such as silicon, which is currently the most commonly used. Basically, when light strikes the cell, a certain portion of it is absorbed within the semiconductor material. This means that the energy of the absorbed light is transferred to the semiconductor. The energy knocks electrons loose, allowing them to flow freely. PV cells also all have one or more electric fields that act to force electrons freed by light absorption to flow in a certain direction. This flow of electrons is a current, and by placing metal contacts on the top and bottom of the PV cell, we can draw that current off to use externally. For example, the current can power a calculator. This current, together with the cell's voltage (which is a result of its built-in electric field or fields), defines the power (or wattage) that the solar cell can produce.

That's the basic process, but there's really much more to it. Let's take a deeper look into one example of a PV cell: the single crystal silicon cell.


Silicon in Solar Cells
Silicon has some special chemical properties, especially in its crystalline form. An atom of silicon has 14 electrons, arranged in three different shells. The first two shells, those closest to the center, are completely full. The outer shell, however, is only half full, having only four electrons. A silicon atom will always look for ways to fill up its last shell (which would like to have eight electrons). To do this, it will share electrons with four of its neighbor silicon atoms. It's like every atom holds hands with its neighbors, except that in this case, each atom has four hands joined to four neighbors. That's what forms the crystalline structure, and that structure turns out to be important to this type of PV cell.

We've now described pure, crystalline silicon. Pure silicon is a poor conductor of electricity because none of its electrons are free to move about, as electrons are in good conductors such as copper. Instead, the electrons are all locked in the crystalline structure. The silicon in a solar cell is modified slightly so that it will work as a solar cell.

Our cell has silicon with impurities -- other atoms mixed in with the silicon atoms, changing the way things work a bit. We usually think of impurities as something undesirable, but in our case, our cell wouldn't work without them. These impurities are actually put there on purpose. Consider silicon with an atom of phosphorous here and there, maybe one for every million silicon atoms. Phosphorous has five electrons in its outer shell, not four. It still bonds with its silicon neighbor atoms, but in a sense, the phosphorous has one electron that doesn't have anyone to hold hands with. It doesn't form part of a bond, but there is a positive proton in the phosphorous nucleus holding it in place.

When energy is added to pure silicon, for example in the form of heat, it can cause a few electrons to break free of their bonds and leave their atoms. A hole is left behind in each case. These electrons then wander randomly around the crystalline lattice looking for another hole to fall into. These electrons are called free carriers, and can carry electrical current. There are so few of them in pure silicon, however, that they aren't very useful. Our impure silicon with phosphorous atoms mixed in is a different story. It turns out that it takes a lot less energy to knock loose one of our "extra" phosphorous electrons because they aren't tied up in a bond -- their neighbors aren't holding them back. As a result, most of these electrons do break free, and we have a lot more free carriers than we would have in pure silicon. The process of adding impurities on purpose is called doping, and when doped with phosphorous, the resulting silicon is called N-type ("n" for negative) because of the prevalence of free electrons. N-type doped silicon is a much better conductor than pure silicon is.

Actually, only part of our cell is N-type. The other part is doped with boron, which has only three electrons in its outer shell instead of four, to become P-type silicon. Instead of having free electrons, P-type silicon ("p" for positive) has free holes. Holes really are just the absence of electrons, so they carry the opposite (positive) charge. They move around just like electrons do.

So where has all this gotten us? The interesting part starts when you put N-type silicon together with P-type silicon. Remember that every PV cell has at least one electric field. Without an electric field, the cell wouldn't work, and this field forms when the N-type and P-type silicon are in contact. Suddenly, the free electrons in the N side, which have been looking all over for holes to fall into, see all the free holes on the P side, and there's a mad rush to fill them in.

Before now, our silicon was all electrically neutral. Our extra electrons were balanced out by the extra protons in the phosphorous. Our missing electrons (holes) were balanced out by the missing protons in the boron. When the holes and electrons mix at the junction between N-type and P-type silicon, however, that neutrality is disrupted. Do all the free electrons fill all the free holes? No. If they did, then the whole arrangement wouldn't be very useful. Right at the junction, however, they do mix and form a barrier, making it harder and harder for electrons on the N side to cross to the P side. Eventually, equilibrium is reached, and we have an electric field separating the two sides.


This electric field acts as a diode, allowing (and even pushing) electrons to flow from the P side to the N side, but not the other way around. It's like a hill -- electrons can easily go down the hill (to the N side), but can't climb it (to the P side).

So we've got an electric field acting as a diode in which electrons can only move in one direction. Let's see what happens when light hits the cell.

When Light Hits the Cell
When light, in the form of photons, hits our solar cell, its energy frees electron-hole pairs.
Each photon with enough energy will normally free exactly one electron, and result in a free hole as well. If this happens close enough to the electric field, or if free electron and free hole happen to wander into its range of influence, the field will send the electron to the N side and the hole to the P side. This causes further disruption of electrical neutrality, and if we provide an external current path, electrons will flow through the path to their original side (the P side) to unite with holes that the electric field sent there, doing work for us along the way. The electron flow provides the current, and the cell's electric field causes a voltage. With both current and voltage, we have power, which is the product of the two.


How much sunlight energy does our PV cell absorb? Unfortunately, the most that our simple cell could absorb is around 25 percent, and more likely is 15 percent or less. Why so little?

Finishing the Cell
There are a few more steps left before we can really use our cell. Silicon happens to be a very shiny material, which means that it is very reflective. Photons that are reflected can't be used by the cell. For that reason, an antireflective coating is applied to the top of the cell to reduce reflection losses to less than 5 percent.
The final step is the glass cover plate that protects the cell from the elements. PV modules are made by connecting several cells (usually 36) in series and parallel to achieve useful levels of voltage and current, and putting them in a sturdy frame complete with a glass cover and positive and negative terminals on the back.


Single crystal silicon isn't the only material used in PV cells. Polycrystalline silicon is also used in an attempt to cut manufacturing costs, although resulting cells aren't as efficient as single crystal silicon. Amorphous silicon, which has no crystalline structure, is also used, again in an attempt to reduce production costs. Other materials used include gallium arsenide, copper indium diselenide and cadmium telluride. Since different materials have different band gaps, they seem to be "tuned" to different wavelengths, or photons of different energies. One way efficiency has been improved is to use two or more layers of different materials with different band gaps. The higher band gap material is on the surface, absorbing high-energy photons while allowing lower-energy photons to be absorbed by the lower band gap material beneath. This technique can result in much higher efficiencies. Such cells, called multi-junction cells, can have more than one electric field.



Enti

Được enti sửa chữa / chuyển vào 17/07/2002 ngày 00:48

chủ đề này hay đấy,nhưng tiếc là không thể đọc được!
Mylife is limit(hic!hic!),while knowledge is endless!!


Felix

Mình có ý kiến là : bạn post tiếng anh cũng được , nhưng sau đó thì dịch hộ luôn hoặc nếu không bảo mọi người dịch hộ cũng được , như vậy box ta sẽ học tiếng anh luôn .
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